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41.
乙酰丙酮荧光分光光度法测定环境空气中的微量甲醛 总被引:25,自引:0,他引:25
建立了乙酰丙酮荧光分光光度法测定空气中微量甲醛的方法,选择了最佳实验条件,考察了多种共存物的影响及最大允许量.该方法最低检出限为0.0034μg/ml,相对标准偏差为5.6%,测定空气中甲醛的最低浓度为0.0057mg/m3,可满足室内外环境空气中甲醛本底及受甲醛污染环境的监测. 相似文献
42.
活性污泥对甲醛废水的净化性能 总被引:4,自引:1,他引:3
采用微生物法处理低浓度甲醛废水达标排放是比较经济的方法之一.在研究中采用序批式活性污泥法(SBR)工艺,考察了曝气时间、进水甲醛浓度、进水 pH 和水温对微生物净化低浓度甲醛废水的影响.结果表明,随着曝气时间的延长,活性污泥对甲醛的去除率增大.进水甲醛浓度在 40~120 mg/L 范围内,随着浓度升高甲醛污泥负荷增加,微生物对甲醛的降解速率增加,但对甲醛的去除率降低.活性污泥在 pH 为 5~7 的中性和弱酸性环境中对甲醛的降解速率较高.在15~35℃范围内,污泥对废水中甲醛的去除率随温度升高而上升,微生物对甲醛的降解速率随温度升高呈指数递增趋势. 相似文献
43.
44.
大气甲醛(HCHO)是臭氧(O3)和细颗粒物(PM2.5)二次组分的关键前体物,在大气光化学反应和二次污染形成过程中扮演着重要角色,并存在致癌性.然而,当前对大气HCHO排放来源认识存在不足,制约了二次污染形成机制研究和污染防控策略制定.采用排放因子和成分谱结合方法,建立2006~2020年广东省HCHO排放趋势清单,识别了广东省主要HCHO排放来源和排放时空演变特征.结果表明,2006~2020年期间广东省HCHO排放量在3.9~5.6万t区间波动,整体呈现极微弱的下降趋势;生物质燃烧源是广东省重要HCHO排放源,而受到管控措施的显著影响,其排放量占比从2006年的58%降至2020年的27%;溶剂使用源的HCHO排放则逐渐突显,2020年占比增长至28%,并成为广东省首要排放源,其中塑料制品和沥青铺路是主要贡献行业.移动源中以柴油作为燃料的工程机械和货车也是HCHO重要排放来源;虽然珠三角和非珠三角地区对广东省HCHO排放量贡献相当,但空间分布结果表明HCHO排放热点区域分别集中于珠三角中心区域和非珠三角的东西两角,这是由于珠三角主要来源为溶剂使用源和移动源,而非珠三角主要受生物质燃烧源影响.因此,未来应进一步加强珠三角中心区域的工业和移动源减排以及粤西地区的生物质燃烧监管. 相似文献
45.
为探究过氧化物酶体增殖物激活受体γ/解偶联蛋白2(PPARγ/UCP2)在甲醛(FA)诱导的学习记忆障碍中的作用,本文将C57BL/6小鼠随机分为:对照组、T0070907组(抑制剂组)、3mg/m3 FA组、3mg/m3 FA+T0070907组,进行连续21d的实验暴露,在第22d取脑组织测定脑组织脏体比并匀浆,检测活性氧(ROS)、谷胱甘肽(GSH)、丙二醛(MDA)、核因子κB (NF-κB)、白细胞介素6(IL-6)、PPARγ、UCP2等生化指标,通过Nissl染色观察脑组织的病理学变化.结果发现,与对照组相比,T0070907组和3mg/m3 FA组小鼠大脑皮层神经元受损,GSH含量下降,ROS、MDA、NF-κB、IL-6含量有所上升,而3mg/m3 FA+T0070907组小鼠上述现象更严重.此外,与对照组相比,T0070907组小鼠脑组织中的PPARγ和UCP2含量下降,但3mg/m3 FA组小鼠脑组织中的PPARγ和UCP2含量上升;与3mg/m3 FA组相比,加入抑制剂的3mg/m3 FA+T0070907组小鼠脑组织中的PPARγ和UCP2含量下降.研究结果表明,在加入PPARγ抑制剂后,PPARγ/UCP2含量下降,加重了FA所致小鼠的学习记忆障碍,故PPARγ/UCP2在FA致学习记忆障碍中可能起保护作用. 相似文献
46.
Once contaminate the drinking water source, antibiotic resistance genes (ARGs) will propagate in drinking water systems and pose a serious risk to human health. Therefore, the drinking water treatment processes (DWTPs) are critical to manage the risks posed by ARGs. This study summarizes the prevalence of ARGs in raw water sources and treated drinking water worldwide. In addition, the removal efficiency of ARGs and related mechanisms by different DWTPs are reviewed. Abiotic and biotic factors that affect ARGs elimination are also discussed. The data on presence of ARGs in drinking water help come to the conclusion that ARGs pollution is prevalent and deserves a high priority. Generally, DWTPs indeed achieve ARGs removal, but some biological treatment processes such as biological activated carbon filtration may promote antibiotic resistance due to the enrichment of ARGs in the biofilm. The finding that disinfection and membrane filtration are superior to other DWTPs adds weight to the advice that DWTPs should adopt multiple disinfection barriers, as well as keep sufficient chlorine residuals to inhibit re-growth of ARGs during subsequent distribution. Mechanistically, DWTPs obtain direct and inderect ARGs reduction through DNA damage and interception of host bacterias of ARGs. Thus, escaping of intracellular ARGs to extracellular environment, induced by DWTPs, should be advoided. This review provides the theoretical support for developping efficient reduction technologies of ARGs. Future study should focus on ARGs controlling in terms of transmissibility or persistence through DWTPs due to their biological related nature and ubiquitous presence of biofilm in the treatment unit. 相似文献
47.
Nowadays, iron ions as a ubiquitous heavy metal pollutant are gradually concerned and the convenient and quick removal of excessive iron ions in groundwater has become a major challenge for the safety of drinking water. In this study, boron-doped biochar (B-BC) was successfully prepared at various preparation conditions with the addition of boric acid. The as-prepared material has a more developed pore structure and a larger specific surface area (up to 897.97 m²/g). A series of characterization results shows that boric acid effectively activates biochar, and boron atoms are successfully doped on biochar. Compared with the ratio of raw materials, the pyrolysis temperature has a greater influence on the amount of boron doping. Based on Langmuir model, the maximum adsorption capacity of 800B-BC1:2 at 25 °C, 40 °C, 55 °C are 50.02 mg/g, 95.09 mg/g, 132.78 mg/g, respectively. Pseudo-second-order kinetic model can better describe the adsorption process, the adsorption process is mainly chemical adsorption. Chemical complexation, ions exchange, and co-precipitation may be the main mechanisms for Fe2+ removal. 相似文献
48.
Oliver Manlik Robert C. Lacy William B. Sherwin Hugh Finn Neil R. Loneragan Simon J. Allen 《Conservation biology》2022,36(4):e13897
Human-caused mortality of wildlife is a pervasive threat to biodiversity. Assessing the population-level impact of fisheries bycatch and other human-caused mortality of wildlife has typically relied upon deterministic methods. However, population declines are often accelerated by stochastic factors that are not accounted for in such conventional methods. Building on the widely applied potential biological removal (PBR) equation, we devised a new population modeling approach for estimating sustainable limits to human-caused mortality and applied it in a case study of bottlenose dolphins affected by capture in an Australian demersal otter trawl fishery. Our approach, termed sustainable anthropogenic mortality in stochastic environments (SAMSE), incorporates environmental and demographic stochasticity, including the dependency of offspring on their mothers. The SAMSE limit is the maximum number of individuals that can be removed without causing negative stochastic population growth. We calculated a PBR of 16.2 dolphins per year based on the best abundance estimate available. In contrast, the SAMSE model indicated that only 2.3–8.0 dolphins could be removed annually without causing a population decline in a stochastic environment. These results suggest that reported bycatch rates are unsustainable in the long term, unless reproductive rates are consistently higher than average. The difference between the deterministic PBR calculation and the SAMSE limits showed that deterministic approaches may underestimate the true impact of human-caused mortality of wildlife. This highlights the importance of integrating stochasticity when evaluating the impact of bycatch or other human-caused mortality on wildlife, such as hunting, lethal control measures, and wind turbine collisions. Although population viability analysis (PVA) has been used to evaluate the impact of human-caused mortality, SAMSE represents a novel PVA framework that incorporates stochasticity for estimating acceptable levels of human-caused mortality. It offers a broadly applicable, stochastic addition to the demographic toolbox to evaluate the impact of human-caused mortality on wildlife. 相似文献
49.
The potential of commonly available green alga Ulva lactuca was investigated as viable biomaterials for removal of synthetic azo dye (Direct Yellow 12, DY-12) from aqueous solution. The results obtained from the batch experiments revealed that the ability of the U. lactuca to remove DY-12 from its aqueous solution was dependent on the dye concentration, pH, and algal biomass but less dependent on the particle size of the U. lactuca. The equilibrium conditions and kinetics of adsorption were investigated, and the adsorption kinetic was consistent with the pseudo-second-order model (R2=1). The adsorption isotherm followed only the Freundlich model with a correlation coefficient R2=0.99. This study demonstrated that the U. lactuca could be used as an effective biosorbent for the removal of DY-12 from its aqueous solution. 相似文献
50.